One-Pot Synthesis of a bis-Pocket Corrole through a 14-fold Bromination Reaction
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چکیده
منابع مشابه
One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
A one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris(2,6-dibromo-3,5-dimethoxyphenyl)corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to MnIII and AuIII. A single-crystal X-ray structure was o...
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ژورنال
عنوان ژورنال: ChemistryOpen
سال: 2017
ISSN: 2191-1363
DOI: 10.1002/open.201600168